29 CFR § 1915.1000 Air contaminants | Code of Federal Regulations | US Law

29 CFR § 1915.1000

Air contaminants

July 28, 2023

CFR

§ 1915.1000 Air contaminants.

Wherever this section applies, an employee's exposure to any substance listed in Table Z—Shipyards of this section shall be limited in accordance with the requirements of the following paragraphs of this section.

(a)

(1) Substances with limits preceded by “C”—Ceiling values. An employee's exposure to any substance in Table Z—Shipyards, the exposure limit of which is preceded by a “C,” shall at no time exceed the exposure limit given for that substance. If instantaneous monitoring is not feasible, then the ceiling shall be assessed as a 15-minute time weighted average exposure which shall not be exceeded at any time over a working day.

(2) Other Substances—8-hour Time Weighted Averages. An employee's exposure to any substance in Table Z—Shipyards, the exposure limit of which is not preceded by a “C,” shall not exceed the 8-hour Time Weighted Average given for that substance in any 8-hour work shift of a 40-hour work week.

(b)–(c) [Reserved]

(d) Computation formula. The computation formula which shall apply to employee exposure to more than one substance for which 8-hour time weighted averages are listed in subpart Z of 29 CFR part 1915 in order to determine whether an employee is exposed over the regulatory limit is as follows:

(1)

(i) The cumulative exposure for an 8-hour work shift shall be computed as follows:

E = (C_a T_a + C_b T_b + ...C_n T_n) ÷ 8

Where:

E is the equivalent exposure for the working shift.

C is the concentration during any period of time T where the concentration remains constant.

T is the duration in hours of the exposure at the concentration C.

The value of E shall not exceed the 8-hour time weighted average specified in subpart Z of 29 CFR part 1915 for the material involved.

(ii) To illustrate the formula prescribed in paragraph (d)(1)(i) of this section, assume that Substance A has an 8-hour time weighted average limit of 100 ppm noted in Table Z—Shipyards. Assume that an employee is subject to the following exposure:

Two hours exposure at 150 ppm

Two hours exposure at 75 ppm

Four hours exposure at 50 ppm

Substituting this information in the formula, we have

(2 × 150 + 2 × 75 + 4 × 50) ÷ 8 = 81.25 ppm

Since 81.25 ppm is less than 100 ppm, the 8-hour time weighted average limit, the exposure is acceptable.

(2)

(i) in case of a mixture of air contaminants an employer shall compute the equivalent exposure as follows:

E_m = (C₁ ÷ L₁ + C₂ ÷ L₂) + ...(C_n ÷ L_n)

Where:

E_m is the equivalent exposure for the mixture.

C is the concentration of a particular contaminant.

L is the exposure limit for that substance specified in subpart Z of 29 CFR part 1915.

The value of E_m shall not exceed unity (1).

(ii) To illustrate the formula prescribed in paragraph (d)(2)(i) of this section, consider the following exposures:

Open Table

Substance	Actual concentration of 8 hour exposure (ppm)	8 hr. TWA PEL (ppm)
B	500	1000
C	45	200
D	40	200

Since Em is less than unity (1), the exposure combination is within acceptable limits.

Table Z—Shipyards

Open Table

Substance	CAS No.^d	ppm^{a *}	mg/m^{3 b *}	Skin Designation
Abate; see Temephos
Acetaldehyde	75–07–0	200	360	—
Acetic acid	64–19–7	10	25	—
Acetic anhydride	108–24–7	5	20	—
Acetone	67–64–1	1000	2400	—
Acetonitrile	75–05–8	40	70	—
2-Acetylaminofluorine; see § 1915.1014	53–96–3
Acetylene	74–86–2	E
Acetylene dichloride; see 1,2-Dichloroethylene
Acetylene tetrabromide	79–27–6	1	14	—
Acrolein	107–02–8	0.1	0.25	—
Acrylamide	79–06–1	—	0.3	X
Acrylonitrile; see § 1915.1045	107–13–1
Aldrin	309–00–2	—	0.25	X
Allyl alcohol	107–18–6	2	5	X
Allyl chloride	107–05–1	1	3	—
Allyl glycidyl ether (AGE)	106–92–3	(C)10	(C)45	—
Allyl propyl disulfide	2179–59–1	2	12	—
alpha-Alumina	1344–28–1
Total dust		—	15	—
Respirable fraction		—	5	—
Aluminum, (as Al) Metal	7429–90–5
Total dust		—	15	—
Respirable fraction		—	5	—
Alundum; see alpha-Alumina
4-Aminodiphenyl; see § 1915.1011	92–67–1
2-Aminoethanol; see Ethanolamine
2-Aminopyridine	504–29–0	0.5	2	—
Ammonia	7664–41–7	50	35	—
Ammonium sulfamate	7773–06–0
Total dust		—	15	—
Respirable fraction		—	5	—
n-Amyl acetate	628–63–7	100	525	—
sec-Amyl acetate	626–38–0	125	650	—
Aniline and homologs	62–53–3	5	19	X
Anisidine (o-, p-isomers)	29191–52–4	—	0.5	X
Antimony and compounds (as Sb)	7440–36–0	—	0.5	—
ANTU (alpha Naphthylthiourea)	86–88–4	—	0.3	—
Argon	7440–37–1	E
Arsenic, inorganic compounds (as As); see § 1915.1018	7440–38–2	—	—	—
Arsenic, organic compounds (as As)	7440–38–2	—	0.5	—
Arsine	7784–42–1	0.05	0.2	—
Asbestos; see 1915.1001
Azinphos-methyl	86–50–0	—	0.2	X
Barium, soluble compounds (as Ba)	7440–39–3	—	0.5	—
Barium sulfate	7727–43–7
Total dust		—	15	—
Respirable fraction		—	5	—
Benomyl	17804–35–2
Total dust		—	15	—
Respirable fraction		—	5	—
Benzene^g; see § 1915.1028	71–43–2
Benzidine; see § 1915.1010	92–87–5
p-Benzoquinone; see Quinone
Benzo(a)pyrene; see Coal tar pitch volatiles
Benzoyl peroxide	94–36–0	—	5	—
Benzyl chloride	100–44–7	1	5	—
Beryllium and beryllium compounds (as Be); see 1915.1024^(q)	7440–41–7		0.002
Biphenyl; see Diphenyl
Bismuth telluride, Undoped	1304–82–1
Total dust		—	15	—
Respirable fraction		—	5	—
Bisphenol A; see Diglycidyl ether
Boron oxide	1303–86–2
Total dust		—	15	—
Boron tribromide	10294–33–4	1	10	—
Boron trifluoride	7637–07–2	(C)1	(C)3	—
Bromine	7726–95–6	0.1	0.7	—
Bromine pentafluoride	7789–30–2	0.1	0.7	—
Bromoform	75–25–2	0.5	5	X
Butadiene (1,3-Butadiene); see 29 CFR 1910.1051; 29 CFR 1910.19(l)	106–99–0	1 ppm/5 ppm STEL	—	—
Butanethiol; see Butyl mercaptan
2-Butanone (Methyl ethyl ketone)	78–93–3	200	590	—
2-Butoxyethanol	111–76–2	50	240	X
n-Butyl-acetate	123–86–4	150	710	—
sec-Butyl acetate	105–46–4	200	950	—
tert-Butyl acetate	540–88–5	200	950	—
n-Butyl alcohol	71–36–3	100	300	—
sec-Butyl alcohol	78–92–2	150	450	—
tert-Butyl alcohol	75–65–0	100	300	—
Butylamine	109–73–9	(C)5	(C)15	X
tert-Butyl chromate (as CrO₃); see 1915.1026ⁿ	1189–85–1
n-Butyl glycidyl ether (BGE)	2426–08–6	50	270	—
Butyl mercaptan	109–79–5	0.5	1.5	—
p-tert-Butyltoluene	98–51–1	10	60	—
Cadmium dust fume (as Cd); see 1915.1027	7440–43–9	—	—	—
Calcium carbonate	1317–65–3
Total dust		—	15	—
Respirable fraction		—	5	—
Calcium hydroxide	1305–62–0	—	—	—
Calcium hydroxide
Total dust		—	15	—
Respirable fraction		—	5	—
Calcium oxide	1305–78–8	—	5	—
Calcium silicate	1344–95–2
Total dust		—	15	—
Respirable fraction		—	5	—
Calcium sulfate	7778–18–9
Total dust		—	15	—
Respirable fraction		—	5	—
Camphor, synthetic	76–22–2	—	2	—
Carbaryl (Sevin)	63–25–2	—	5	—
Carbon black	1333–86–4	—	3.5	—
Carbon dioxide	124–38–9	5000	9000	—
Carbon disulfide	75–15–0	20	60	X
Carbon monoxide	630–08–0	50	55	—
Carbon tetrachloride	56–23–5	10	65	X
Cellulose	9004–34–6
Total dust		—	15	—
Respirable fraction		—	5	—
Chlordane	57–74–9	—	0.5	X
Chlorinated camphene	8001–35–2	—	0.5	X
Chlorinated diphenyl oxide	55720–99–5	—	0.5	—
Chlorine	7782–50–5	1	3	—
Chlorine trifluoride	7790–91–2	(C)0.1	(C)0.4	—
Chloroacetaldehyde	107–20–0	(C)1	(C)3	—
a-Chloroacetophenone (Phenacyl chloride)	532–27–4	0.05	0.3	—
Chlorobenzene	108–90–7	75	350	—
o-Chlorobenzylidene malononitrile	2698–41–1	0.05	0.4	—
Chlorobromomethane	74–97–5	200	1050	—
2-Chloro-1,3-butadiene; see beta-Chloroprene
Chlorodiphenyl (42% Chlorine) (PCB)	53469–21–9	—	1	X
Chlorodiphenyl (54% Chlorine) (PCB)	11097–69–1	—	0.5	X
1-Chloro,2,3-epoxypropane; see Epichlorohydrin
2-Chloroethanol; see Ethylene chlorohydrin
Chloroethylene; see Vinyl chloride
Chloroform (Trichloromethane)	67–66–3	50	240	—
bis(Chloromethyl) ether; see § 1915.1008	542–88–1
Chloromethyl methyl ether; see § 1915.1006	107–30–2
1-Chloro-1-nitropropane	600–25–9	20	100	—
Chloropicrin	76–06–2	0.1	0.7
beta-Chloroprene	126–99–8	25	90	X
2-Chloro-6-(trichloromethyl) pyridine	1929–82–4
Total dust		—	15	—
Respirable fraction		—	5	—
Chromium (II) compounds
(as Cr)	7440–47–3	—	0.5	—
Chromium (III) compounds
(as Cr)	7440–47–3	—	0.5	—
Chromium (VI) compounds; see 1915.1026^o
Chromium metal and insol. salts (as Cr)	7440–47–3	—	1	—
Chrysene; see Coal tar pitch volatiles
Clopidol	2971–90–6
Total dust		—	15	—
Respirable fraction		—	5	—
Coal tar pitch volatiles (benzene soluble fraction), anthracene, BaP, phenanthrene, acridine, chrysene, pyrene	65966–93–2	—	0.2	—
Cobalt metal, dust, and fume (as Co)	7440–48–4	—	0.1	—
Copper	7440–50–8
Fume (as Cu)		—	0.1	—
Dusts and mists (as Cu)		—	1	—
Corundum; see Emery
Cotton dust (raw)		—	1
Crag herbicide (Sesone)	136–78–7
Total dust		—	15	—
Respirable fraction		—	5	—
Cresol, all isomers	1319–77–3	5	22	X
Crotonaldehyde	123–73–9;	2	6
	4170–30–3
Cumene	98–82–8	50	245	X
Cyanides (as CN)	Varies with Compound	—	5	—
Cyanogen	460–19–5	10	—	—
Cyclohexane	110–82–7	300	1050	—
Cyclohexanol	108–93–0	50	200	—
Cyclohexanone	108–94–1	50	200	—
Cyclohexene	110–83–8	300	1015	—
Cyclonite	121–82–4	—	1.5	X
Cyclopentadiene	542–92–7	75	200	—
2,4-D (Dichlorophenoxyacetic acid)	94–75–7	—	10	—
Decaborane	17702–41–9	0.05	0.3	X
Demeton (Systox)	8065–48–3	—	0.1	X
Diacetone alcohol (4-Hydroxy-4-methyl-2-pentanone)	123–42–2	50	240	—
1,2-Diaminoethane; see Ethylenediamine
Diazomethane	334–88–3	0.2	0.4	—
Diborane	19287–45–7	0.1	0.1	—
1,2-Dibromo-3-chloropropane (CBCP); see § 1915.1044	96–12–8		—
1,2-Dibromoethane; see Ethylene dibromide
Dibutyl phosphate	107–66–4	1	5	—
Dibutyl phthalate	84–74–2	—	5	—
Dichloroacetylene	7572–29–4	(C)0.1	(C)0.4	—
o-Dichlorobenzene	95–50–1	(C)50	(C)300	—
p-Dichlorobenzene	106–46–7	75	450	—
3,3′-Dichlorobenzidine; see § 1915.1007	91–94–1
Dichlorodifluoromethane	75–71–8	1000	4950	—
1,3-Dichloro-5,5-dimethyl hydantoin	118–52–5	—	0.2	—
Dichlorodiphenyltrichloroethane (DDT)	50–29–3	—	1	X
1,1-Dichloroethane	75–34–3	100	400	—
1,2-Dichloroethane; see Ethylene dichloride
1,2-Dichloroethylene	540–59–0	200	790	—
Dichloroethyl ether	111–44–4	(C)15	(C)90	X
Dichloromethane; see Methylene chloride
Dichloromonofluoromethane	75–43–4	1000	4200	—
1,1-Dichloro-1-nitroethane	594–72–9	(C)10	(C)60	—
1,2-Dichloropropane; see Propylene dichloride
Dichlorotetrafluoroethane	76–14–2	1000	7000	—
Dichlorvos (DDVP)	62–73–7	—	1	X
Dicyclopentadienyl iron	102–54–5
Total dust		—	15	—
Respirable fraction		—	5	—
Dieldrin	60–57–1	—	0.25	X
Diethylamine	109–89–7	25	75	—
2-Diethylaminoethanol	100–37–8	10	50	—
Diethylene triamine	111–40–0	(C)10	(C)42	X
Diethyl ether; see Ethyl ether
Difluorodibromomethane	75–61–6	100	860	—
Diglycidyl ether (DGE)	2238–07–5	(C)0.5	(C)2.8	—
Dihydroxybenzene; see Hydroquinone
Diisobutyl ketone	108–83–8	50	290	—
Diisopropylamine	108–18–9	5	20	X
4-Dimethylaminoazobenzene; see § 1915.1015	60–11–7
Dimethoxymethane; see Methylal
Dimethyl acetamide	127–19–5	10	35	X
Dimethylamine	124–40–3	10	18	—
Dimethylaminobenzene; see Xylidine
Dimethylaniline (N,N-Dimethylaniline)	121–69–7	5	25	X
Dimethylbenzene; see Xylene
Dimethyl-1,2-dibromo- 2,2-dichloroethyl phosphate	300–76–5	—	3	—
Dimethylformamide	68–12–2	10	30	X
2,6-Dimethyl-4-heptanone; see Diisobutyl ketone
1,1-Dimethylhydrazine	57–14–7	0.5	1	X
Dimethylphthalate	131–11–3	—	5	—
Dimethyl sulfate	77–78–3	1	5	X
Dinitrobenzene (all isomers)			1	X
(ortho)	528–29–0
(meta)	99–65–0
(para)	100–25–4
Dinitro-o-cresol	534–52–1	—	0.2	X
Dinitrotoluene	25321–14–6	—	1.5	X
Dioxane (Diethylene dioxide)	123–91–1	100	360	X
Diphenyl (Biphenyl)	92–52–4	0.2	1	—
Diphenylamine	122–39–4	—	10	—
Diphenylmethane diisocyanate; see Methylene bisphenyl isocyanate
Dipropylene glycol methyl ether	34590–94–8	100	600	X
Di-sec octyl phthalate (Di-(2-ethylhexyl) phthalate)	117–81–7	—	5	—
Emery	12415–34–8
Total dust		—	15	—
Respirable fraction		—	5	—
Endosulfan	115–29–7	—	0.1	X
Endrin	72–20–8	—	0.1	X
Epichlorohydrin	106–89–8	5	19	X
EPN	2104–64–5	—	0.5	X
1,2-Epoxypropane; see Propylene oxide
2,3-Epoxy-1-propanol; see Glycidol
Ethane	74–84–0	E
Ethanethiol; see Ethyl mercaptan
Ethanolamine	141–43–5	3	6	—
2-Ethoxyethanol (Cellosolve)	110–80–5	200	740	X
2-Ethoxyethyl acetate (Cellosolve acetate)	111–15–9	100	540	X
Ethyl acetate	141–78–6	400	1400	—
Ethyl acrylate	140–88–5	25	100	X
Ethyl alcohol (Ethanol)	64–17–5	1000	1900	—
Ethylamine	75–04–7	10	18	—
Ethyl amyl ketone (5-Methyl-3-heptanone)	541–85–5	25	130	—
Ethyl benzene	100–41–4	100	435	—
Ethyl bromide	74–96–4	200	890	—
Ethyl butyl ketone (3-Heptanone)	106–35–4	50	230	—
Ethyl chloride	75–00–3	1000	2600	—
Ethyl ether	60–29–7	400	1200	—
Ethyl formate	109–94–4	100	300	—
Ethyl mercaptan	75–08–1	0.5	1	—
Ethyl silicate	78–10–4	100	850	—
Ethylene	74–85–1	E
Ethylene chlorohydrin	107–07–3	5	16	X
Ethylenediamine	107–15–3	10	25	—
Ethylene dibromide	106–93–4	(C)25	(C)190	X
Ethylene dichloride (1,2-Dichloroethane)	107–06–2	50	200	—
Ethylene glycol dinitrate	628–96–6	(C)0.2	(C)1	X
Ethylene glycol methyl acetate; see Methyl cellosolve acetate
Ethyleneimine; see § 1915.1012	151–56–4
Ethylene oxide; see § 1915.1047	75–21–8
Ethylidene chloride; see 1,1-Dichloroethane
N-Ethylmorpholine	100–74–3	20	94	X
Ferbam	14484–64–1
Total dust		—	15	—
Ferrovanadium dust	12604–58–9	—	1	—
Fibrous Glass
Total dust			15	—
Respirable fraction		—	5	—
Fluorides (as F)	Varies with compound	—	2.5	—
Fluorine	7782–41–4	0.1	0.2	—
Fluorotrichloromethane (Trichlorofluoromethane)	75–69–4	1000	5600	—
Formaldehyde; see § 1915.1048	50–00–0
Formic acid	64–18–6	5	9	—
Furfural	98–01–1	5	20	X
Furfuryl alcohol	98–00–0	50	200	—
Gasoline	8006–61–9		A³	—
Glycerin (mist)	56–81–5
Total dust		—	15	—
Respirable fraction		—	5	—
Glycidol	556–52–5	50	150	—
Glycol monoethyl ether; see 2-Ethoxyethanol
Graphite, natural, respirable dust	7782–42–5	(²)	(²)	(²)
Graphite, synthetic
Total dust		—	15	—
Respirable fraction		—	5	—
Guthion; see Azinphos methyl
Gypsum	13397–24–5
Total dust		—	15	—
Respirable fraction		—	5	—
Hafnium	7440–58–6	—	0.5	—
Helium	7440–59–7	E
Heptachlor	76–44–8	—	0.5	X
Heptane (n-Heptane)	142–82–5	500	2000	—
Hexachloroethane	67–72–1	1	10	X
Hexachloronaphthalene	1335–87–1	—	0.2	X
n-Hexane	110–54–3	500	1800	—
2-Hexanone (Methyl n-butyl ketone)	591–78–6	100	410	—
Hexone (Methyl isobutyl ketone)	108–10–1	100	410	—
sec-Hexyl acetate	108–84–9	50	300	—
Hydrazine	302–01–2	1	1.3	X
Hydrogen	1333–74–0	E
Hydrogen bromide	10035–10–6	3	10	—
Hydrogen chloride	7647–01–0	(C)5	(C)7	—
Hydrogen cyanide	74–90–8	10	11	X
Hydrogen fluoride (as F)	7664–39–3	3	2	—
Hydrogen peroxide	7722–84–1	1	1.4	—
Hydrogen selenide (as Se)	7783–07–5	0.05
Hydrogen sulfide	7783–06–4	10	15	—
Hydroquinone	123–31–9	—	2	—
Indene	95–13–6	10	45	—
Indium and compounds (as In)	7440–74–6	—	0.1	—
Iodine	7553–56–2	(C)0.1	(C)1	—
Iron oxide fume	1309–37–1	—	10	—
Iron salts (soluble) (as Fe)	Varies with compound	—	1	—
Isoamyl acetate	123–92–2	100	525	—
Isoamyl alcohol (primary and secondary)	123–51–3	100	360	—
Isobutyl acetate	110–19–0	150	700	—
Isobutyl alcohol	78–83–1	100	300	—
Isophorone	78–59–1	25	140	—
Isopropyl acetate	108–21–4	250	950	—
Isopropyl alcohol	67–63–0	400	980	—
Isopropylamine	75–31–0	5	12	—
Isopropyl ether	108–20–3	500	2100	—
Isopropyl glycidyl ether (IGE)	4016–14–2	50	240	—
Kaolin	1332–58–7
Total dust		—	15	—
Respirable fraction		—	5	—
Ketene	463–51–4	0.5	0.9	—
Lead, inorganic (as Pb); see § 1915.1025	7439–92–1	—	—	—
Limestone	1317–65–3
Total dust		—	15	—
Respirable fraction		—	5	—
Lindane	58–89–9	—	0.5	X
Lithium hydride	7580–67–8	—	0.025	—
L.P.G. (Liquefied petroleum gas)	68476–85–7	1000	1800
Magnesite	546–93–0
Total dust		—	15	—
Respirable fraction		—	5	—
Magnesium oxide fume	1309–48–4
Total particulate		15	—	—
Malathion	121–75–5
Total dust		—	15	X
Maleic anhydride	108–31–6	0.25
Manganese compounds (as Mn)	7439–96–5	—	(C)5	—
Manganese fume (as Mn)	7439–96–5	—	(C)5	—
Marble	1317–65–3
Total dust		—	15	—
Respirable fraction		—	5	—
Mercury (aryl and inorganic)(as Hg)	7439–97–6		0.1	X
Mercury (organo) alkyl compounds (as Hg)	7439–97–6	—	0.01	X
Mercury (vapor) (as Hg)	7439–97–6	—	0.1	X
Mesityl oxide	141–79–7	25	100	—
Methane	74–82–8	E
Methanethiol; see Methyl mercaptan
Methoxychlor	72–43–5
Total dust		—	15	—
2-Methoxyethanol (Methyl cellosolve)	109–86–4	25	80	X
2-Methoxyethyl acetate (Methyl cellosolve acetate)	110–49–6	25	120	X
Methyl acetate	79–20–9	200	610	—
Methyl acetylene (Propyne)	74–99–7	1000	1650	—
Methyl acetylene-propadiene mixture (MAPP)		1000	1800	—
Methyl acrylate	96–33–3	10	35	X
Methylal (Dimethoxy-methane)	109–87–5	1000	3100	—
Methyl alcohol	67–56–1	200	260	—
Methylamine	74–89–5	10	12	—
Methyl amyl alcohol; see Methyl isobutyl carbinol
Methyl n-amyl ketone	110–43–0	100	465	—
Methyl bromide	74–83–9	(C)20	(C)80	X
Methyl butyl ketone; see 2-Hexanone
Methyl cellosolve; see 2-Methoxyethanol
Methyl cellosolve acetate; see 2-Methoxyethyl acetate
Methyl chloride	74–87–3	100	210	—
Methyl chloroform (1,1,1-Trichloroethane)	71–55–6	350	1900	—
Methylcyclohexane	108–87–2	500	2000	—
Methylcyclohexanol	25639–42–3	100	470	—
o-Methylcyclohexanone	583–60–8	100	460	X
Methylene chloride; see § 1910.1052
Methyl ethyl ketone (MEK); see 2-Butanone
Methyl formate	107–31–3	100	250	—
Methyl hydrazine (Monomethyl hydrazine)	60–34–4	(C)0.2	(C)0.35	X
Methyl iodide	74–88–4	5	28	X
Methyl isoamyl ketone	110–12–3	100	475	—
Methyl isobutyl carbinol	108–11–2	25	100	X
Methyl isobutyl ketone; see Hexone
Methyl isocyanate	624–83–9	0.02	0.05	X
Methyl mercaptan	74–93–1	0.5	1	—
Methyl methacrylate	80–62–6	100	410	100
Methyl propyl ketone; see 2-Pentanone
Methyl silicate	681–84–5	5	30	—
alpha-Methyl styrene	98–83–9	(C)100	(C)480	—
Methylene bisphenyl isocyanate (MDI)	101–68–8	(C)0.02	(C)0.2	—
Mica; see Silicates
Mineral wool
Total dust		—	15	—
Respirable dust		—	5	—
Molybdenum (as Mo)	7439–98–7
Soluble compounds		—	5	—
Insoluble compounds
Total dust		—	15	—
Monomethyl aniline	100–61–8	2	9	X
Monomethyl hydrazine; see Methyl hydrazine
Morpholine	110–91–8	20	70	X
Naphtha (Coal tar)	8030–30–6	100	400	—
Naphthalene	91–20–3	10	50	—
alpha-Naphthylamine; see § 1915.1004	134–32–7
beta-Naphthylamine; see § 1915.1009	91–59–8			—
Neon	7440–01–9
Nickel carbonyl (as Ni)	13463–39–3	0.001	0.007	—
Nickel, metal and insoluble compounds (as Ni)	7440–02–0	—	1	—
Nickel, soluble compounds (as Ni)	7440–02–0	—	1	—
Nicotine	54–11–5	—	0.5	X
Nitric acid	7697–37–2	2	5	—
Nitric oxide	10102–43–9	25	30	—
p-Nitroaniline	100–01–6	1	6	X
Nitrobenzene	98–95–3	1	5	X
p-Nitrochlorobenzene	100–00–5	—	1	X
4-Nitrodiphenyl; see § 1915.1003	92–93–3
Nitroethane	79–24–3	100	310	—
Nitrogen	7727–37–9	E
Nitrogen dioxide	10102–44–0	(C)5	(C)9	—
Nitrogen trifluoride	7783–54–2	10	29	—
Nitroglycerin	55–63–0	(C)0.2	(C)2	X
Nitromethane	75–52–5	100	250	—
1-Nitropropane	108–03–2	25	90	—
2-Nitropropane	79–46–9	25	90	—
N-Nitrosodimethylamine; see § 1915.1016	62–79–9			—
Nitrotoluene (all isomers)		5	30	X
o-isomer	88–72–2;
m-isomer	99–08–1;
p-isomer	99–99–0
Nitrotrichloromethane; see Chloropicrin
Nitrous oxide	10024–97–2	E
Octachloronaphthalene	2234–13–1	—	0.1	X
Octane	111–65–9	400	1900	—
Oil mist, mineral	8012–95–1	—	5	—
Osmium tetroxide (as Os)	20816–12–0	—	0.002	—
Oxalic acid	144–62–7	—	1	—
Oxygen difluoride	7783–41–7	0.05	0.1	—
Ozone	10028–15–6	0.1	0.2	—
Paraquat, respirable dust	4685–14–7;	—	0.5	X
	1910–42–5;
	2074–50–2
Parathion	56–38–2	—	0.1	—
Particulates not otherwise regulated
Total dust organic and inorganic		—	15	—
PCB; see Chlorodiphenyl (42% and 54% chlorine)
Pentaborane	19624–22–7	0.005	0.01	—
Pentachloronaphthalene	1321–64–8	—	0.5	X
Pentachlorophenol	87–86–5	—	0.5	X
Pentaerythritol	115–77–5
Total dust		—	15	—
Respirable fraction		—	5	—
Pentane	109–66–0	500	1500	—
2-Pentanone (Methyl propyl ketone)	107–87–9	200	700	—
Perchloroethylene (Tetrachloroethylene)	127–18–4	100	670	—
Perchloromethyl mercaptan	594–42–3	0.1	0.8	—
Perchloryl fluoride	7616–94–6	3	13.5	—
Perlite	93763–70–3
Total dust		—	15	—
Respirable fraction		—	5	—
Petroleum distillates (Naphtha)(Rubber Solvent)			A³	—
Phenol	108–95–2	5	19	X
p-Phenylene diamine	106–50–3	—	0.1	X
Phenyl ether, vapor	101–84–8	1	7	—
Phenyl ether-biphenyl mixture, vapor		1	7	—
Phenylethylene; see Styrene
Phenyl glycidyl ether (PGE)	122–60–1	10	60	—
Phenylhydrazine	100–63–0	5	22	X
Phosdrin (Mevinphos)	7786–34–7	—	0.1	X
Phosgene (Carbonyl chloride)	75–44–5	0.1	0.4	—
Phosphine	7803–51–2	0.3	0.4	—
Phosphoric acid	7664–38–2	—	1	—
Phosphorus (yellow)	7723–14–0	—	0.1	—
Phosphorus pentachloride	10026–13–8	—	1	—
Phosphorus pentasulfide	1314–80–3	—	1	—
Phosphorus trichloride	7719–12–2	0.5	3	—
Phthalic anhydride	85–44–9	2	12	—
Picloram	1918–02–1
Total dust		—	15	—
Respirable fraction		—	5	—
Picric acid	88–89–1	—	0.1	—
Piperazine dihydrochloride	142–64–3	—	—	X
Pindone (2-Pivalyl-1,3-indandione)	83–26–1	—	0.1	—
Plaster of Paris	26499–65–0
Total dust		—	15	—
Respirable fraction		—	5	—
Platinum (as Pt)	7440–06–4
Metal		—	—	—
Soluble salts		—	0.002	—
Polytetrafluoroethylene decomposition products			A²
Portland cement	65997–15–1
Total dust		15	—	10
Respirable fraction		5	—	—
Propargyl alcohol	107–19–7	1	—	X
beta-Propriolactone; see § 1915.1013	57–57–8
Propionic acid	79–09–4	—	—	—
n-Propyl acetate	109–60–4	200	840	—
n-Propyl alcohol	71–23–8	200	500	—
n-Propyl nitrate	627–13–4	25	110	—
Propylene dichloride	78–87–5	75	350	—
Propylene imine	75–55–8	2	5	X
Propylene oxide	75–56–9	100	240	—
Propyne; see Methyl acetylene
Pyrethrum	8003–34–7	—	5	—
Pyridine	110–86–1	5	15	—
Quinone	106–51–4	0.1	0.4	—
RDX; see Cyclonite
Rhodium (as Rh), metal fume and insoluble compounds	7440–16–6	—	0.1	—
Rhodium (as Rh), soluble compounds	7440–16–6	—	0.001	—
Ronnel	299–84–3	—	10	—
Rotenone	83–79–4	—	5	—
Rouge		—
Total dust		—	15	—
Respirable fraction		—	5	—
Selenium compounds (as Se)	7782–49–2	—	0.2	—
Selenium hexafluoride (as Se)	7783–79–1	0.05	0.4	—
Silica, amorphous, precipitated and gel	112926–00–8	(²)	(²)	(²)
Silica, amorphous, diatomaceous earth, containing less than 1% crystalline silica	61790–53–2	(²)	(²)	(²)
Silica, crystalline, respirable dust
Cristobalite; see 1915.1053	14464–46–1
Quartz; see 1915.1053⁵	14808–60–7
Tripoli (as quartz); see 1915.1053⁵	1317–95–9
Tridymite; see 1915.1053	15468–32–3
Silica, fused, respirable dust	60676–86–0	(²)	(²)	(²)
Silicates (less than 1% crystalline silica)
Mica (respirable dust)	12001–26–2	(²)	(²)	(²)
Soapstone, total dust	—	(²)	(²)	(²)
Soapstone, respirable dust	—	(²)	(²)	(²)
Talc (containing asbestos)	—	(³)	(³)	(³)
Talc (containing no asbestos), respirable dust	14807–96–6	(²)	(²)	(²)
Tremolite, asbestiform		(³)	(³)	(³)
Silicon	7440–21–3
Total dust		—	15	—
Respirable fraction		—	5	—
Silicon carbide	409–21–2
Total dust		—	15	—
Respirable fraction		—	5	—
Silver, metal and soluble compounds (as Ag)	7440–22–4	—	0.01	—
Soapstone; see Silicates
Sodium fluoroacetate	62–74–8	—	0.05	X
Sodium hydroxide	1310–73–2	—	2	—
Starch	9005–25–8
Total dust		—	15	—
Respirable fraction		—	5	—
Stibine	7803–52–3	0.1	0.5	—
Stoddard solvent	8052–41–3	200	1150	—
Strychnine	57–24–9	—	0.15	—
Styrene	100–42–5	100	420	50
Sucrose	57–50–1
Total dust		—	15	—
Respirable fraction		—	5	—
Sulfur dioxide	7446–09–5	5	13	—
Sulfur hexafluoride	2551–62–4	1000	6000	—
Sulfuric acid	7664–93–9	—	1	—
Sulfur monochloride	10025–67–9	1	6	—
Sulfur pentafluoride	5714–22–7	0.025	0.25	—
Sulfuryl fluoride	2699–79–8	5	20	—
Systox, see Demeton
2,4,5-T (2,4,5-trichlorophenoxyacetic acid)	93–76–5	—	10	—
Talc; see Silicates—
Tantalum, metal and oxide dust	7440–25–7	—	5	—
TEDP (Sulfotep)	3689–24–5	—	0.2	X
Teflon decomposition products			A2
Tellurium and compounds (as Te)	13494–80–9	—	0.1	—
Tellurium hexafluoride (as Te)	7783–80–4	0.02	0.2	—
Temephos	3383–96–8
Total dust		—	15	—
Respirable fraction		—	5	—
TEPP (Tetraethyl pyrophosphate)	107–49–3	—	0.05	X
Terphenyls	26140–60–3	(C)1	(C)9	—
1,1,1,2-Tetrachloro-2,2-difluoroethane	76–11–9	500	4170	—
1,1,2,2-Tetrachloro-1,2-difluoroethane	76–12–0	500	4170	—
1,1,2,2-Tetrachloroethane	79–34–5	5	35	X
Tetrachloroethylene; see Perchloroethylene
Tetrachloromethane; see Carbon tetrachloride
Tetrachloronaphthalene	1335–88–2	—	2	X
Tetraethyl lead (as Pb)	78–00–2	—	0.1	X
Tetrahydrofuran	109–99–9	200	590	—
Tetramethyl lead, (as Pb)	75–74–1	—	0.15	X
Tetramethyl succinonitrile	3333–52–6	0.5	3	X
Tetranitromethane	509–14–8	1	8	—
Tetryl (2,4,6-Trinitrophenylmethylnitramine)	479–45–8	—	1.5	X
Thallium, soluble compounds (as Tl)	7440–28–0	—	0.1	X
4,4′-Thiobis (6-tert, Butyl-m-cresol)	96–69–5
Total dust		—	15	—
Respirable fraction		—	5	—
Thiram	137–26–8	—	5	—
Tin, inorganic compounds (except oxides) (as Sn)	7440–31–5	—	2	—
Tin, organic compounds (as Sn)	7440–31–5	—	0.1	—
Tin oxide (as Sn)	21651–19–4	—	—	—
Total dust		—	15	—
Respirable fraction		—	5	—
Titanium dioxide	13463–67–7
Total dust		—	15	—
Toluene	108–88–3	200	750	100
Toluene-2,4-diisocyanate (TDI)	584–84–9	(C)0.02	(C)0.14	—
o-Toluidine	95–53–4	5	22	X
Toxaphene; see Chlorinated camphene
Tremolite; see Silicates
Tributyl phosphate	126–73–8	—	5	—
1,1,1-Trichloroethane; see Methyl chloroform
1,1,2-Trichloroethane	79–00–5	10	45	X
Trichloroethylene	79–01–6	100	535	—
Trichloromethane; see Chloroform
Trichloronaphthalene	1321–65–9	—	5	X
1,2,3-Trichloropropane	96–18–4	50	300	—
1,1,2-Trichloro-1,2,2-trifluoroethane	76–13–1	1000	7600	—
Triethylamine	121–44–8	25	100	—
Trifluorobromomethane	75–63–8	1000	6100	—
Trimethyl benzene	25551–13–7	25	120	—
2,4,6-Trinitrophenyl; see Picric acid
2,4,6-Trinitrophenylmethylnitramine; see Tetryl
2,4,6-Trinitrotoluene (TNT)	118–96–7	—	1.5	X
Triorthocresyl phosphate	78–30–8	—	0.1	—
Triphenyl phosphate	115–86–6	—	3	—
Tungsten (as W)	7440–33–7
Insoluble compounds		—	5	—
Soluble compounds		—	1	—
Turpentine	8006–64–2	100	560	—
Uranium (as U)	7440–61–1
Soluble compounds		—	0.2	—
Insoluble compounds		—	0.2	—
Vanadium	1314–62–1
Respirable dust (as V₂ O₅)		—	(C)0.5	—
Fume (as V₂ O₅)		—	(C)0.1	—
Vegetable oil mist
Total dust		—	15	—
Respirable fraction		—	5	—
Vinyl benzene; see Styrene
Vinyl chloride; see § 1915.1017	75–01–4
Vinyl cyanide; see Acrylonitrile
Vinyl toluene	25013–15–4	100	480	—
Warfarin	81–81–2	—	0.1	—
Xylenes (o-, m-, p-isomers)	1330–20–7	100	435	—
Xylidine	1300–73–8	5	25	X
Yttrium	7440–65–5	—	1	—
Zinc chloride fume	7646–85–7	—	1	—
Zinc oxide fume	1314–13–2	—	5	—
Zinc oxide	1314–13–2
Total dust		—	15	—
Respirable fraction		—	5	—
Zinc stearate	557–05–1
Total dust		—	15	—
Respirable fraction		—	5	—
Zirconium compounds (as Zr)	7440–67–7	—	5

Mineral Dusts

Open Table

Substance	mppcf^(j)
SILICA:
Crystalline	250^(k)
Quartz. Threshold Limit calculated from the formula^(p)	% SiO₂ + 5
Cristobalite
Amorphous, including natural diatomaceous earth	20
SILICATES (less than 1% crystalline silica)
Mica	20
Portland cement	50
Soapstone	20
Talc (non-asbestiform)	20
Talc (fibrous), use asbestos limit	—
Graphite (natural)	15
Inert or Nuisance Particulates:^(m)	50 (or 15 mg/m³ whichever is the smaller) of total dust <1% SiO₂
Conversion factors
mppcf × 35.3 = million particles per cubic meter = particles per c.c.

Open Table

Footnotes to Table Z—Shipyards:

¹ [Reserved]

² See Mineral Dusts Table.

³ Use Asbestos Limit § 1915.1001.

⁴ See 1915.1001.

⁵ See Mineral Dusts table for the exposure limit for any operations or sectors where the exposure limit in § 1915.1053 is stayed or is otherwise not in effect.

* The PELs are 8-hour TWAs unless otherwise noted; a (C) designation denotes a ceiling limit. They are to be determined from breathing-zone air samples.

^a Parts of vapor or gas per million parts of contaminated air by volume at 25 °C and 760 torr.

^b Milligrams of substance per cubic meter of air. When entry is in this column only, the value is exact; when listed with a ppm entry, it is approximate.

^c [Reserved]

^d The CAS number is for information only. Enforcement is based on the substance name. For an entry covering more than one metal compound, measured as the metal, the CAS number for the metal is given—not CAS numbers for the individual compounds.

^e–f [Reserved]

^g For sectors excluded from § 1915.1028 the limit is 10 ppm TWA.

^h Where OSHA has published a proposal for a substance but has not issued a final rule, the proposal is referenced and the existing limit is published.

ⁱ [Reserved]

^j Millions of particles per cubic foot of air, based on impinger samples counted by light-field techniques.

^k The percentage of crystalline silica in the formula is the amount determined from airborne samples, except in those instances in which other methods have been shown to be applicable.

^m Covers all organic and inorganic particulates not otherwise regulated. Same as Particulates Not Otherwise Regulated.

ⁿ If the exposure limit in § 1915.1026 is stayed or is otherwise not in effect, the exposure limit is a ceiling of 0.1 mg/m³.

^o If the exposure limit in § 1915.1026 is stayed or is otherwise not in effect, the exposure limit is 0.1 mg/m³ (as CrO₃) as an 8-hour TWA.

^p This standard applies to any operations or sectors for which the respirable crystalline silica standard, 1915.1053, is stayed or otherwise is not in effect.

^q This standard applies to any operations or sectors for which the beryllium standard, 1915.1024, is stayed or otherwise is not in effect.

The 1970 TLV uses letter designations instead of a numerical value as follows:

A¹ [Reserved]

A² Polytetrafluoroethylene decomposition products. Because these products decompose in part by hydrolysis in alkaline solution, they can be quantitatively determined in air as fluoride to provide an index of exposure. No TLV is recommended pending determination of the toxicity of the products, but air concentrations should be minimal.

A³ Gasoline and/or Petroleum Distillates. The composition of these materials varies greatly and thus a single TLV for all types of these materials is no longer applicable. The content of benzene, other aromatics and additives should be determined to arrive at the appropriate TLV.

E Simple asphyxiants. The limiting factor is the available oxygen which shall be at least 18% and be within the requirement addressing explosion in subpart B of part 1915.

[58 FR 35514, July 1, 1993, as amended at 61 FR 56856, Nov. 4, 1996; 62 FR 1619, Jan. 10, 1997; 67 FR 44545, July 3, 2002; 71 FR 10377, Feb. 28, 2006; 71 FR 36009, June 23, 2006; 76 FR 80740, Dec. 27, 2011; 81 FR 16874, Mar. 2 2016; 81 FR 31167, May 19, 2016; 81 FR 60273, Sept. 2, 2016; 82 FR 2744, Jan. 9, 2017]

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