40 CFR Table A-1 to Subpart A of Part 98
Global Warming Potentials
June 9, 2020
CFR

[100-Year Time Horizon]

Open Table
Name CAS No. Chemical formula Global
warming
potential
(100 yr.)
Chemical-Specific GWPs
Carbon dioxide 124-38-9 CO2 1
Methane 74-82-8 CH4 a25
Nitrous oxide 10024-97-2 N2O a298
Fully Fluorinated GHGs
Sulfur hexafluoride 2551-62-4 SF6 a22,800
Trifluoromethyl sulphur pentafluoride 373-80-8 SF5CF3 17,700
Nitrogen trifluoride 7783-54-2 NF3 17,200
PFC-14 (Perfluoromethane) 75-73-0 CF4 a7,390
PFC-116 (Perfluoroethane) 76-16-4 C2F6 a12,200
PFC-218 (Perfluoropropane) 76-19-7 C3F8 a8,830
Perfluorocyclopropane 931-91-9 C-C3F6 17,340
PFC-3-1-10 (Perfluorobutane) 355-25-9 C4F10 a8,860
PFC-318 (Perfluorocyclobutane) 115-25-3 C-C4F8 a10,300
PFC-4-1-12 (Perfluoropentane) 678-26-2 C5F12 a9,160
PFC-5-1-14 (Perfluorohexane, FC-72) 355-42-0 C6F14 a9,300
PFC-6-1-12 335-57-9 C7F16; CF3(CF2)5CF3 b7,820
PFC-7-1-18 307-34-6 C8F18; CF3(CF2)6CF3 b7,620
PFC-9-1-18 306-94-5 C10F18 7,500
PFPMIE (HT-70) NA CF3OCF(CF3)CF2OCF2OCF3 10,300
Perfluorodecalin (cis) 60433-11-6 Z-C10F18 b7,236
Perfluorodecalin (trans) 60433-12-7 E-C10F18 b6,288
Saturated Hydrofluorocarbons (HFCs) With Two or Fewer Carbon-Hydrogen Bonds
HFC-23 75-46-7 CHF3 a14,800
HFC-32 75-10-5 CH2F2 a675
HFC-125 354-33-6 C2HF5 a3,500
HFC-134 359-35-3 C2H2F4 a1,100
HFC-134a 811-97-2 CH2FCF3 a1,430
HFC-227ca 2252-84-8 CF3CF2CHF2 b2640
HFC-227ea 431-89-0 C3HF7 a3,220
HFC-236cb 677-56-5 CH2FCF2CF3 1,340
HFC-236ea 431-63-0 CHF2CHFCF3 1,370
HFC-236fa 690-39-1 C3H2F6 a9,810
HFC-329p 375-17-7 CHF2CF2CF2CF3 b2360
HFC-43-10mee 138495-42-8 CF3CFHCFHCF2CF3 a1,640
Saturated Hydrofluorocarbons (HFCs) With Three or More Carbon-Hydrogen Bonds
HFC-41 593-53-3 CH3F a92
HFC-143 430-66-0 C2H3F3 a353
HFC-143a 420-46-2 C2H3F3 a4,470
HFC-152 624-72-6 CH2FCH2F 53
HFC-152a 75-37-6 CH3CHF2 a124
HFC-161 353-36-6 CH3CH2F 12
HFC-245ca 679-86-7 C3H3F5 a693
HFC-245cb 1814-88-6 CF3CF2CH3 b4620
HFC-245ea 24270-66-4 CHF2CHFCHF2 b235
HFC-245eb 431-31-2 CH2FCHFCF3 b290
HFC-245fa 460-73-1 CHF2CH2CF3 1,030
HFC-263fb 421-07-8 CH3CH2CF3 b76
HFC-272ca 420-45-1 CH3CF2CH3 b144
HFC-365mfc 406-58-6 CH3CF2CH2CF3 794
Saturated Hydrofluoroethers (HFEs) and Hydrochlorofluoroethers (HCFEs) With One Carbon-Hydrogen Bond
HFE-125 3822-68-2 CHF2OCF3 14,900
HFE-227ea 2356-62-9 CF3CHFOCF3 1,540
HFE-329mcc2 134769-21-4 CF3CF2OCF2CHF2 919
HFE-329me3 428454-68-6 CF3CFHCF2OCF3 b4,550
1,1,1,2,2,3,3-Heptafluoro-3-(1,2,2,2-tetrafluoroethoxy)-propane 3330-15-2 CF3CF2CF2OCHFCF3 b6,490
Saturated HFEs and HCFEs With Two Carbon-Hydrogen Bonds
HFE-134 (HG-00) 1691-17-4 CHF2OCHF2 6,320
HFE-236ca 32778-11-3 CHF2OCF2CHF2 b4,240
HFE-236ca12 (HG-10) 78522-47-1 CHF2OCF2OCHF2 2,800
HFE-236ea2 (Desflurane) 57041-67-5 CHF2OCHFCF3 989
HFE-236fa 20193-67-3 CF3CH2OCF3 487
HFE-338mcf2 156053-88-2 CF3CF2OCH2CF3 552
HFE-338mmz1 26103-08-2 CHF2OCH(CF3)2 380
HFE-338pcc13 (HG-01) 188690-78-0 CHF2OCF2CF2OCHF2 1,500
HFE-43-10pccc (H-Galden 1040x, HG-11) E1730133 CHF2OCF2OC2F4OCHF2 1,870
HCFE-235ca2 (Enflurane) 13838-16-9 CHF2OCF2CHFCl b583
HCFE-235da2 (Isoflurane) 26675-46-7 CHF2OCHClCF3 350
HG-02 205367-61-9 HF2C-(OCF2CF2)2-OCF2H b3,825
HG-03 173350-37-3 HF2C-(OCF2CF2)3-OCF2H b3,670
HG-20 249932-25-0 HF2C-(OCF2)2-OCF2H b5,300
HG-21 249932-26-1 HF2C-OCF2CF2OCF2OCF2O-CF2H b3,890
HG-30 188690-77-9 HF2C-(OCF2)3-OCF2H b7,330
1,1,3,3,4,4,6,6,7,7,9,9,10,10,12,12,13,13,15,15-eicosafluoro-2,5,8,11,14-Pentaoxapentadecane 173350-38-4 HCF2O(CF2CF2O)4CF2H b3,630
1,1,2-Trifluoro-2-(trifluoromethoxy)-ethane 84011-06-3 CHF2CHFOCF3 b1,240
Trifluoro(fluoromethoxy)methane 2261-01-0 CH2FOCF3 b751
Saturated HFEs and HCFEs With Three or More Carbon-Hydrogen Bonds
HFE-143a 421-14-7 CH3OCF3 756
HFE-245cb2 22410-44-2 CH3OCF2CF3 708
HFE-245fa1 84011-15-4 CHF2CH2OCF3 286
HFE-245fa2 1885-48-9 CHF2OCH2CF3 659
HFE-254cb2 425-88-7 CH3OCF2CHF2 359
HFE-263fb2 460-43-5 CF3CH2OCH3 11
HFE-263m1; R-E-143a 690-22-2 CF3OCH2CH3 b29
HFE-347mcc3 (HFE-7000) 375-03-1 CH3OCF2CF2CF3 575
HFE-347mcf2 171182-95-9 CF3CF2OCH2CHF2 374
HFE-347mmy1 22052-84-2 CH3OCF(CF3)2 343
HFE-347mmz1 (Sevoflurane) 28523-86-6 (CF3)2CHOCH2F c216
HFE-347pcf2 406-78-0 CHF2CF2OCH2CF3 580
HFE-356mec3 382-34-3 CH3OCF2CHFCF3 101
HFE-356mff2 333-36-8 CF3CH2OCH2CF3 b17
HFE-356mmz1 13171-18-1 (CF3)2CHOCH3 27
HFE-356pcc3 160620-20-2 CH3OCF2CF2CHF2 110
HFE-356pcf2 50807-77-7 CHF2CH2OCF2CHF2 265
HFE-356pcf3 35042-99-0 CHF2OCH2CF2CHF2 502
HFE-365mcf2 22052-81-9 CF3CF2OCH2CH3 b58
HFE-365mcf3 378-16-5 CF3CF2CH2OCH3 11
HFE-374pc2 512-51-6 CH3CH2OCF2CHF2 557
HFE-449s1 (HFE-7100) Chemical blend 163702-07-6 C4F9OCH3 297
    163702-08-7 (CF3)2CFCF2OCH3
HFE-569sf2 (HFE-7200) Chemical blend 163702-05-4 C4F9OC2H5 59
    163702-06-5 (CF3)2CFCF2OC2H5
HG'-01 73287-23-7 CH3OCF2CF2OCH3 b222
HG'-02 485399-46-0 CH3O(CF2CF2O)2CH3 b236
HG'-03 485399-48-2 CH3O(CF2CF2O)3CH3 b221
Difluoro(methoxy)methane 359-15-9 CH3OCHF2 b144
2-Chloro-1,1,2-trifluoro-1-methoxyethane 425-87-6 CH3OCF2CHFCl b122
1-Ethoxy-1,1,2,2,3,3,3-heptafluoropropane 22052-86-4 CF3CF2CF2OCH2CH3 b61
2-Ethoxy-3,3,4,4,5-pentafluorotetrahydro-2,5-bis[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-furan 920979-28-8 C12H5F19O2 b56
1-Ethoxy-1,1,2,3,3,3-hexafluoropropane 380-34-7 CF3CHFCF2OCH2CH3 b23
Fluoro(methoxy)methane 460-22-0 CH3OCH2F b13
1,1,2,2-Tetrafluoro-3-methoxy-propane; Methyl 2,2,3,3-tetrafluoropropyl ether 60598-17-6 CHF2CF2CH2OCH3 b0.5
1,1,2,2-Tetrafluoro-1-(fluoromethoxy)ethane 37031-31-5 CH2FOCF2CF2H b871
Difluoro(fluoromethoxy)methane 461-63-2 CH2FOCHF2 b617
Fluoro(fluoromethoxy)methane 462-51-1 CH2FOCH2F b130
Fluorinated Formates
Trifluoromethyl formate 85358-65-2 HCOOCF3 b588
Perfluoroethyl formate 313064-40-3 HCOOCF2CF3 b580
1,2,2,2-Tetrafluoroethyl formate 481631-19-0 HCOOCHFCF3 b470
Perfluorobutyl formate 197218-56-7 HCOOCF2CF2CF2CF3 b392
Perfluoropropyl formate 271257-42-2 HCOOCF2CF2CF3 b376
1,1,1,3,3,3-Hexafluoropropan-2-yl formate 856766-70-6 HCOOCH(CF3)2 b333
2,2,2-Trifluoroethyl formate 32042-38-9 HCOOCH2CF3 b33
3,3,3-Trifluoropropyl formate 1344118-09-7 HCOOCH2CH2CF3 b17
Fluorinated Acetates
Methyl 2,2,2-trifluoroacetate 431-47-0 CF3COOCH3 b52
1,1-Difluoroethyl 2,2,2-trifluoroacetate 1344118-13-3 CF3COOCF2CH3 b31
Difluoromethyl 2,2,2-trifluoroacetate 2024-86-4 CF3COOCHF2 b27
2,2,2-Trifluoroethyl 2,2,2-trifluoroacetate 407-38-5 CF3COOCH2CF3 b7
Methyl 2,2-difluoroacetate 433-53-4 HCF2COOCH3 b3
Perfluoroethyl acetate 343269-97-6 CH3COOCF2CF3 b2.1
Trifluoromethyl acetate 74123-20-9 CH3COOCF3 b2.0
Perfluoropropyl acetate 1344118-10-0 CH3COOCF2CF2CF3 b1.8
Perfluorobutyl acetate 209597-28-4 CH3COOCF2CF2CF2CF3 b1.6
Ethyl 2,2,2-trifluoroacetate 383-63-1 CF3COOCH2CH3 b1.3
Carbonofluoridates
Methyl carbonofluoridate 1538-06-3 FCOOCH3 b95
1,1-Difluoroethyl carbonofluoridate 1344118-11-1 FCOOCF2CH3 b27
Fluorinated Alcohols Other Than Fluorotelomer Alcohols
Bis(trifluoromethyl)-methanol 920-66-1 (CF3)2CHOH 195
(Octafluorotetramethy-lene) hydroxymethyl group NA X-(CF2)4CH(OH)-X 73
2,2,3,3,3-Pentafluoropropanol 422-05-9 CF3CF2CH2OH 42
2,2,3,3,4,4,4-Heptafluorobutan-1-ol 375-01-9 C3F7CH2OH b25
2,2,2-Trifluoroethanol 75-89-8 CF3CH2OH b20
2,2,3,4,4,4-Hexafluoro-1-butanol 382-31-0 CF3CHFCF2CH2OH b17
2,2,3,3-Tetrafluoro-1-propanol 76-37-9 CHF2CF2CH2OH b13
2,2-Difluoroethanol 359-13-7 CHF2CH2OH b3
2-Fluoroethanol 371-62-0 CH2FCH2OH b1.1
4,4,4-Trifluorobutan-1-ol 461-18-7 CF3(CH2)2CH2OH b0.05
Unsaturated Perfluorocarbons (PFCs)
PFC-1114; TFE 116-14-3 CF2 = CF2; C2F4 b0.004
PFC-1216; Dyneon HFP 116-15-4 C3F6; CF3CF = CF2 b0.05
PFC C-1418 559-40-0 c-C5F8 b1.97
Perfluorobut-2-ene 360-89-4 CF3CF = CFCF3 b1.82
Perfluorobut-1-ene 357-26-6 CF3CF2CF = CF2 b0.10
Perfluorobuta-1,3-diene 685-63-2 CF2 = CFCF = CF2 b0.003
Unsaturated Hydrofluorocarbons (HFCs) and Hydrochlorofluorocarbons (HCFCs)
HFC-1132a; VF2 75-38-7 C2H2F2 , CF2 = CH2 b0.04
HFC-1141; VF 75-02-5 C2H3F, CH2 = CHF b0.02
(E)-HFC-1225ye 5595-10-8 CF3CF = CHF(E) b0.06
(Z)-HFC-1225ye 5528-43-8 CF3CF = CHF(Z) b0.22
Solstice 1233zd(E) 102687-65-0 C3H2ClF3; CHCl = CHCF3 b1.34
HFC-1234yf; HFO-1234yf 754-12-1 C3H2F4; CF3CF = CH2 b0.31
HFC-1234ze(E) 1645-83-6 C3H2F4; trans-CF3CH = CHF b0.97
HFC-1234ze(Z) 29118-25-0 C3H2F4; cis-CF3CH = CHF; CF3CH = CHF b0.29
HFC-1243zf; TFP 677-21-4 C3H3F3, CF3CH = CH2 b0.12
(Z)-HFC-1336 692-49-9 CF3CH = CHCF3(Z) b1.58
HFC-1345zfc 374-27-6 C2F5CH = CH2 b0.09
Capstone 42-U 19430-93-4 C6H3F9, CF3(CF2)3CH = CH2 b0.16
Capstone 62-U 25291-17-2 C8H3F13, CF3(CF2)5CH = CH2 b0.11
Capstone 82-U 21652-58-4 C10H3F17, CF3(CF2)7CH = CH2 b0.09
Unsaturated Halogenated Ethers
PMVE; HFE-216 1187-93-5 CF3OCF = CF2 b0.17
Fluoroxene 406-90-6 CF3CH2OCH = CH2 b0.05
Fluorinated Aldehydes
3,3,3-Trifluoro-propanal 460-40-2 CF3CH2CHO b0.01
Fluorinated Ketones
Novec 1230 (perfluoro (2-methyl-3-pentanone)) 756-13-8 CF3CF2C(O)CF (CF3)2 b0.1
Fluorotelomer Alcohols
3,3,4,4,5,5,6,6,7,7,7-Undecafluoroheptan-1-ol 185689-57-0 CF3(CF2)4CH2CH2OH b0.43
3,3,3-Trifluoropropan-1-ol 2240-88-2 CF3CH2CH2OH b0.35
3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-Pentadecafluorononan-1-ol 755-02-2 CF3(CF2)6CH2CH2OH b0.33
3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Nonadecafluoroundecan-1-ol 87017-97-8 CF3(CF2)8CH2CH2OH b0.19
Fluorinated GHGs With Carbon-Iodine Bond(s)
Trifluoroiodomethane 2314-97-8 CF3I b0.4
Other Fluorinated Compounds
Dibromodifluoromethane (Halon 1202) 75-61-6 CBR2F2 b231
2-Bromo-2-chloro-1,1,1-trifluoroethane (Halon-2311/Halothane) 151-67-7 CHBrClCF3 b41
Open Table
Fluorinated GHG Groupd Global
warming
potential
(100 yr.)
Default GWPs for Compounds for Which Chemical-Specific GWPs Are Not Listed Above
Fully fluorinated GHGs 10,000
Saturated hydrofluorocarbons (HFCs) with 2 or fewer carbon-hydrogen bonds 3,700
Saturated HFCs with 3 or more carbon-hydrogen bonds 930
Saturated hydrofluoroethers (HFEs) and hydrochlorofluoroethers (HCFEs) with 1 carbon-hydrogen bond 5,700
Saturated HFEs and HCFEs with 2 carbon-hydrogen bonds 2,600
Saturated HFEs and HCFEs with 3 or more carbon-hydrogen bonds 270
Fluorinated formates 350
Fluorinated acetates, carbonofluoridates, and fluorinated alcohols other than fluorotelomer alcohols 30
Unsaturated perfluorocarbons (PFCs), unsaturated HFCs, unsaturated hydrochlorofluorocarbons (HCFCs), unsaturated halogenated ethers, unsaturated halogenated esters, fluorinated aldehydes, and fluorinated ketones 1
Fluorotelomer alcohols 1
Fluorinated GHGs with carbon-iodine bond(s) 1
Other fluorinated GHGs 2,000

aThe GWP for this compound was updated in the final rule published on November 29, 2013 [78 FR 71904] and effective on January 1, 2014.

bThis compound was added to Table A-1 in the final rule published on December 11, 2014, and effective on January 1, 2015.

cThe GWP for this compound was updated in the final rule published on December 11, 2014, and effective on January 1, 2015 .

dFor electronics manufacturing (as defined in §98.90), the term “fluorinated GHGs” in the definition of each fluorinated GHG group in §98.6 shall include fluorinated heat transfer fluids (as defined in §98.98), whether or not they are also fluorinated GHGs.

[79 FR 73779, Dec. 11, 2014]


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